CUED Publications database

Structural-failure resistance of metal-organic frameworks toward multiple-cycle CO<inf>2</inf> sorption

Hu, Z and Sun, Y and Zeng, K and Zhao, D (2017) Structural-failure resistance of metal-organic frameworks toward multiple-cycle CO<inf>2</inf> sorption. Chemical Communications, 53. pp. 8653-8656. ISSN 1359-7345

Full text not available from this repository.

Abstract

We present the first study on the structural-failure of MOFs induced by multiple-cycle CO adsorption and desorption, wherein UiO-66(Zr) demonstrates a much better resistance than HKUST-1 in 500-cycle CO adsorption-desorption tests. This conclusion is supported by the higher elastic modulus of UiO-66(Zr) (ca. 28 GPa) and retention of elastic modulus (100%) than HKUST-1 (ca. 19 GPa, 64%) measured via multifrequency atomic force microscopy (MAFM). 2 2

Item Type: Article
Subjects: UNSPECIFIED
Divisions: UNSPECIFIED
Depositing User: Cron Job
Date Deposited: 22 Oct 2019 05:59
Last Modified: 08 Apr 2021 06:19
DOI: 10.1039/c7cc04313a