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Breathing-induced new phase transition in an MIL-53(Al)-NH<inf>2</inf> metal-organic framework under high methane pressures

Bolinois, L and Kundu, T and Wang, X and Wang, Y and Hu, Z and Koh, K and Zhao, D (2017) Breathing-induced new phase transition in an MIL-53(Al)-NH<inf>2</inf> metal-organic framework under high methane pressures. Chemical Communications, 53. pp. 8118-8121. ISSN 1359-7345

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Abstract

The high pressure methane sorption tests on a flexible metal-organic framework [MIL-53(Al)-NH ] reveal a new phase transition to a large pore (lp) phase above 45 bar. The mixed-ligand strategy and pressure cycling tests are suggested to reduce the pressure requirement of such a phase transition for applications in natural gas storage 2

Item Type: Article
Subjects: UNSPECIFIED
Divisions: UNSPECIFIED
Depositing User: Cron Job
Date Deposited: 22 Oct 2019 05:59
Last Modified: 08 Apr 2021 06:19
DOI: 10.1039/c7cc02743e