Solvothermal synthesis of high-performance Ni-Co layered double hydroxide nanofoam electrode for electrochemical energy storage

Patel, R and Inamdar, AI and Hou, B and Cha, SN and Ansari, AT and Gunjakar, JL and Im, H and Kim, H (2017) Solvothermal synthesis of high-performance Ni-Co layered double hydroxide nanofoam electrode for electrochemical energy storage. Current Applied Physics, 17. pp. 501-506. ISSN 1567-1739

Abstract

A nanofoam nickel cobalt layered double hydroxide (NiCo(OH) ) electrode film is fabricated on a stainless-steel substrate with the use of a simple one-step solvothermal process. The nanofoam NiCo(OH) electrode exhibits a high specific capacitance of 2710.2 F/g at a current density of 9.1 A/g, and a good capacity retention of ∼70% after 2000 charge-discharge cycles at a high current density of 31.8 A/g. An energy density of 60.23 Wh/kg is obtained at a power density of 1.8 kW/kg. The excellent electrochemical energy storage performance of the NiCo(OH) electrode is due to the synergetic effect of a significantly improved ionic diffusion and an effective charge transfer, which is linked to a well-dispersed interconnected nanofoam morphology and binder-free direct contact with the current collector. 2 2 2