CUED Publications database

Growth rate of lithium filaments in ceramic electrolytes

Shishvan, SS and Fleck, NA and McMeeking, RM and Deshpande, VS (2020) Growth rate of lithium filaments in ceramic electrolytes. Acta Materialia, 196. pp. 444-455. ISSN 1359-6454

Full text not available from this repository.


© 2020 Lithium-ion batteries with single ion-conductor ceramic electrolytes short-circuit when subjected to charging currents above a critical current density. Here, we analyse the rate at which a lithium (Li) filament (sometimes referred to as a dendrite) will grow from the cathode towards the anode during charging of such batteries. The filament is modelled as a climbing edge dislocation with its growth occurring by Li+ flux from the electrolyte into the filament tip at constant chemical potential. The growth rate is set by a balance between the reduction of free-energy at the filament tip and energy dissipation associated with the resistance to the flux of Li+ through the filament tip. For charging currents above the critical current density, the filament growth rate increases with decreasing filament tip resistance. Imperfections, such as voids in the Li cathode along the electrolyte/cathode interface, decrease the critical current density but filament growth rates are also lower in these cases as filament growth rates scale with the charging currents. The predictions of the model are in excellent quantitative agreement with measurements and confirm that above the critical current density a filament can traverse the electrolyte in minutes or less. This suggests that initiation of filament growth is the critical step to prevent short-circuiting of the battery.

Item Type: Article
Divisions: Div C > Materials Engineering
Depositing User: Cron Job
Date Deposited: 31 Jul 2020 23:19
Last Modified: 17 Sep 2020 03:00
DOI: 10.1016/j.actamat.2020.06.060