CUED Publications database

Dissolving and aligning carbon nanotubes in thermotropic liquid crystals.

Ji, Y and Huang, YY and Terentjev, EM (2011) Dissolving and aligning carbon nanotubes in thermotropic liquid crystals. Langmuir, 27. pp. 13254-13260.

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Abstract

It has been widely recognized that the combination of carbon nanotubes (CNTs) and low molar mass thermotropic liquid crystals (tLCs) not only provides a useful way to align CNTs, but also dramatically enhances the tLC performance especially in the liquid crystal display technology. Such CNT-tLC nanocomposites have ignited hopes to address many stubborn problems within the field, such as low contrast, slow response, and narrow view angle. However, this material development has been limited by the poor solubility of CNTs in tLCs. Here, we describe an effective strategy to solve the problem. Prior to integrating with tLCs, pristine CNTs are physically "coated" by a liquid crystalline polymer (LCP) which is compatible with tLCs. The homogeneous CNT-tLC composite obtained in this way is stable for over 6 months, and the concentration of CNTs in tLCs can reach 1 wt %. We further demonstrate the alignment of CNTs at high CNT concentrations by an electric field with a theory to model the impedance response of the CNT-tLC mixture.

Item Type: Article
Uncontrolled Keywords: Electricity Hot Temperature Liquid Crystals Nanocomposites Nanotubes, Carbon Polymers
Subjects: UNSPECIFIED
Divisions: Div C > Biomechanics
Depositing User: Cron Job
Date Deposited: 07 Mar 2014 11:33
Last Modified: 22 Sep 2014 01:08
DOI: 10.1021/la202790a