CUED Publications database

One pot synthesis of a chiral N-phosphine substituted iminophosphorane: X-ray structure and in situ NMR study

Batsanov, AS and Davidson, MG and Fernández, I and Howard, JAK and López-Ortiz, F and Price, RD (2000) One pot synthesis of a chiral N-phosphine substituted iminophosphorane: X-ray structure and in situ NMR study. Journal of the Chemical Society, Perkin Transactions 1. pp. 4237-4239. ISSN 1470-4358

Full text not available from this repository.

Abstract

An X-ray crystal structure reveals that the attempted deprotonation of cyclopropyl(triphenyl)phosphonium bromide with sodium amide affords a chiral N-phosphine substituted iminophosphorane via an unusual mechanism that has been investigated by multi-nuclear and variable temperature in situ NMR spectroscopy. © The Royal Society of Chemistry 2000.

Item Type: Article
Subjects: UNSPECIFIED
Divisions: Div B > Electronics, Power & Energy Conversion
Div B > Solid State Electronics and Nanoscale Science
Depositing User: Cron Job
Date Deposited: 17 Jul 2017 19:40
Last Modified: 07 Mar 2019 10:50
DOI: 10.1039/b005816p