CUED Publications database

Potential routes to stronger carbon nanotube fibres via carbon ion irradiation and deposition

Mulvihill, DM and O'Brien, NP and Curtin, WA and McCarthy, MA (2016) Potential routes to stronger carbon nanotube fibres via carbon ion irradiation and deposition. Carbon, 96. pp. 1138-1156. ISSN 0008-6223

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Abstract

© 2015 Elsevier Ltd. Fibres made from carbon nanotubes (CNTs) have not yet achieved strengths approaching that of individual CNTs. The problem is that load is not effectively transferred between the constituent, discontinuous CNTs. High energy irradiation has shown promise on small CNT bundles, in creating covalent cross-links to enhance load transfer, but cannot sufficiently penetrate real CNT fibres, which typically contain 10 6 or more CNTs. Here, we suggest that the "draw-twist" process for producing CNT fibres from forests offers an opportunity for CNT bundles to be individually treated with irradiation before being twisted to form a fibre. We use molecular dynamics to examine the effectiveness of low energy (1 eV) carbon ion irradiation (or deposition) in this context. We find that very small amounts of deposition can significantly enhance both intra-bundle and inter-bundle load transfer. Within bundles, deposition atoms mediate covalent links between both the sides and ends of neighbouring CNTs. Inter-bundle load transfer is improved as under-coordinated carbon adatom branches formed during deposition, spontaneously form inter-bundle cross-links as the bundles are forced together by the twisting action. The effects of varying fluence and twisting angles are examined, and the potential to add a prior higher energy irradiation step to pe netrate larger bundles is explored. The possibility to produce an amorphous carbon/CNT composite fibre is also discussed.

Item Type: Article
Subjects: UNSPECIFIED
Divisions: Div C > Materials Engineering
Depositing User: Cron Job
Date Deposited: 17 Jul 2017 19:29
Last Modified: 18 Nov 2017 22:12
DOI: