CUED Publications database

Taming Self-Organization Dynamics to Dramatically Control Porous Architectures

Daly, R and Sader, JE and Boland, JJ (2016) Taming Self-Organization Dynamics to Dramatically Control Porous Architectures. ACS Nano, 10. pp. 3087-3092. ISSN 1936-0851

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Abstract

© 2016 American Chemical Society. We demonstrate templating of functional materials with unexpected and intricate micro- and nanostructures by controlling the condensation, packing, and evaporation of water droplets on a polymer solution. Spontaneous evaporation of a polymer solution induces cooling of the liquid surface and water microdroplet condensation from the ambient vapor. These droplets pack together and act as a template to imprint an entangled polymer film. This breath figure (BF) phenomenon is an example of self-organization that involves the long-range ordering of droplets. Equilibrium-based analysis provides many insights into contact angles and drop stability of individual drops, but the BF phenomenon remains poorly understood thus far, preventing translation to real applications. Here we investigate the dynamics of this phenomenon to separate out the competing influences and then introduce a modulation scheme to ultimately manipulate the water vapor-liquid equilibrium independently from the solvent evaporation. This approach to BF control provides insights into the mechanism, a rationale for microstructure design, and evidence for the benefits of dynamical control of self-organization systems. We finally present dramatically different porous architectures from thi s approach reminiscent of microscale Petri dishes, conical flasks, and test tubes.

Item Type: Article
Subjects: UNSPECIFIED
Divisions: Div E > Production Processes
Depositing User: Cron Job
Date Deposited: 17 Jul 2017 19:32
Last Modified: 23 Nov 2017 03:48
DOI: