CUED Publications database

Chemical routes to discharging graphenides.

Hodge, SA and Buckley, DJ and Yau, HC and Skipper, NT and Howard, CA and Shaffer, MSP (2017) Chemical routes to discharging graphenides. Nanoscale, 9. pp. 3150-3158.

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Abstract

Chemical and electrochemical reduction methods allow the dispersion, processing, and/or functionalization of discrete sp2-hybridised nanocarbons, including fullerenes, nanotubes and graphenes. Electron transfer to the nanocarbon raises the Fermi energy, creating nanocarbon anions and thereby activating an array of possible covalent reactions. The Fermi level may then be partially or fully lowered by intended functionalization reactions, but in general, techniques are required to remove excess charge without inadvertent covalent reactions that potentially degrade the nanocarbon properties of interest. Here, simple and effective chemical discharging routes are demonstrated for graphenide polyelectrolytes and are expected to apply to other systems, particularly nanotubides. The discharging process is inherently linked to the reduction potentials of such chemical discharging agents and the unusual fundamental chemistry of charged nanocarbons.

Item Type: Article
Subjects: UNSPECIFIED
Divisions: Div B > Solid State Electronics and Nanoscale Science
Depositing User: Cron Job
Date Deposited: 25 Jul 2017 03:51
Last Modified: 13 Apr 2021 08:56
DOI: 10.1039/c6nr10004j